Download Advances in electrochemical science and engineering by Richard C. Alkire, Charles W. Tobias PDF

By Richard C. Alkire, Charles W. Tobias

This sequence, previously edited through Heinz Gerischer and Charls V. Tobias, now edited via Richard C. Alkire and Dieter M. Kolb, has been warmly welcomed by way of scientists world-wide that's mirrored within the reports of the former volumes: 'This is a necessary e-book for researchers in electrochemistry; it covers components of either basic and sensible significance, with stories of top of the range. the cloth is particularly good provided and the alternative of subject matters displays a balanced editorial coverage that's welcomed.' The Analyst

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In a similar way, the standard oxidation potentials, E I x , are congruent with those found for the corresponding amines [ 1481. The electrochemical reaction of A-D compounds can be formulated as follows: A-D +e - e A--D (56) A-D -e - e A-D+ (57) After electrochemical reduction an electron is placed in the lowest unoccupied molecular orbital (LUMO) of the acceptor subunits of A-D. In the electrochemical oxidation an electron is removed from the highest occupied molecular orbital (HOMO) of the donor moiety.

Appropriate values of the other terms are not directly available, but some conclusion can be drawn by taking into account the literature data for other similar systems. Relatively large values of V12 are characteristic for aromatic hydrocarbons. 10 eV were found for the electron exchange between anthracene and the anthracene radical anion [ 128,1291. In the alternate hydrocarbon approximation this range of V12 values is expected for electron exchange involving other hydrocarbons (between the parent molecule and the corresponding radical anion or the corresponding radical cation).

24) and (49) have been applied for the calculation of kcT and k3 rates. 030eV for BA and DA, respectively). , their values agree very closely with those estimated for nonradiative [166,167] and radiative [178] electron transfer within ‘(A--A+). The results of the above kinetic calculations ( k 3 / k c ~ ratios) are shown in Fig. 23. The agreement between theory and experiment can be regarded as satisfactory, indicating that the main set of parameters (which seem to be the most probable from a kinetic point of view) introduced into calculations has been correctly selected.

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